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Guanglai LI Renmin HUA Wenlan ZHANG Dongquan HU Xinglin WEI Xiao'e HUANG Lei XIE Junming YAO Xudong WANG 《Resource Geology》2011,61(4):356-366
The Tieshanlong tungsten‐polymetallic deposit is a large wolframite deposit of quartz vein type located in southern Jiangxi, South China. It is genetically related to a high‐K S‐type granite. Seven pyrite and two wolframite samples, selected for He and Ar isotope analyses, yielded 3He/4He values of 0.04–0.98 Ra, 40Ar/36Ar ratios of 293.5–368.0, and 38Ar/36Ar ratios of 0.176–0.193. These data indicate that the ore‐forming fluids associated with the deposit did not result from a simple mixing of the crustal‐ and mantle‐derived end‐member fluids, but that primeval meteoric fluids were also involved in the generation of the associated granitic magma by partial melting of crustal metasedimentary rocks. Further investigations show that only minimal He from the mantle was added during generation of the associated granitic magma. It is postulated that boiling and second mixing with “new” meteoric fluids took place during migration of magmatic‐hydrothermal fluids into wall‐rock fractures, resulting in a drastic decrease of their metal transport capacity, which triggered the tungsten‐polymetallic mineralization. 相似文献
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Fang‐Yue WANG Cong‐Ying LI Ming‐Xing LING Hong ZHANG Ya‐Li SUN Weidong SUN 《Resource Geology》2011,61(4):414-423
Xihuashan tungsten deposit is one of the earliest explored tungsten deposits in southeastern China. It is a vein type deposit genetically associated with the Xihuashan granite pluton. Here we report new dating and zircon geochemistry results. Re–Os isotopic dating for molybdenite intergrowth with wolframite in the oldest generation of the Xihuashan pluton yielded an isochron age of 157.0 ± 2.5 Ma (2σ). Zircon U–Pb laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) dating shows that the pluton crystallized at 155.7 ± 2.2 Ma (2σ). This age is similar to the molybdenite Re–Os age for the ore deposit within error. This, together with published data, suggests that the major W(Mo)‐Sn mineralization occurred between 160–150 Ma in southeastern China. These deposits constitute a major part of the magmatic‐metallogenic belt of eastern Nanlin. The lower Re content in molybdenite of the Xihuashan tungsten deposit shows crustal origin for the ore‐forming material. The limited direct contributions from the subducting slab for the tungsten mineralization in the Nanling region suggest a change of the style of the paleo‐Pacific plate beneath southeastern China. 相似文献
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Xianzhong Cheng Kun Shao Shangyue Shen Shenghong Hu Haiou Qiu 《Geostandards and Geoanalytical Research》2011,35(4):461-469
A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l?1 HNO3. The sample solution in 0.4 mol l?1 HNO3 was pumped through an ESM microcolumn at the rate of 1.0 ml min?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values. 相似文献
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海南石碌铁矿床构造变形特征及其与铁多金属成矿富集的关系 总被引:1,自引:0,他引:1
海南石碌铁矿曾被誉为“亚洲最大的富铁矿”,其形成、定位与褶皱变形及伴随的剪切、塑性流动等构造密切相关。石碌矿区构造变形大致分为早期(D1)复式向斜的形成时期、晚期(D2)褶皱叠加和剪切变形时期。后者又进一步分为韧-脆性变形(D2a),脆-韧性变形、层间滑脱断层形成(D2b)和脆性变形、矿体破坏(D2c)3个阶段。石碌铁矿床受NW—SE向复式向斜及其与NE—NNE向褶皱叠加所形成的横跨或斜跨褶皱的严格控制;褶皱过程所伴随的剪切变形和高温塑性流动是富铁矿形成的重要机制。复式向斜轴部,尤其是2期向斜褶皱轴的叠加部位往往可发现厚大的富铁矿体。 相似文献
109.
西金乌兰-金沙江缝合带东侧原雄松群为一套变基性火山-碎屑岩系,是否属于前寒武系一直存在争议。野外调研期间发现铁矿化线索,初步认为铁矿化与原雄松群变基性火山作用关系密切,并受到印支期二长花岗岩的改造叠加,具有较大成矿潜力。矿石多呈块状、蜂窝状、角砾状,少数呈气泡状、瘤状、绳状。矿石矿物主要为含锰磁铁矿,少量赤铁矿、褐铁矿、孔雀石及氧化残留黄铁矿。捡块样分析, TFe多在50%以上,属于含锰富铁矿。通过LA-ICP-MS锆石微区原位U-Pb同位素测年,赋矿变玄武岩的岩浆喷发时代为(228.3±2.1)Ma,表明该地段雄松群的时代为中三叠世,成矿时代也为中三叠世。含矿变基性火山岩为具E-MORB地球化学特征的拉斑玄武岩系列,指示成矿构造环境可能为小洋盆。铁矿化点与地面高磁异常基本吻合。在金沙江中段甚至更大的范围内,与中三叠世变基性火山岩系(原划雄松群)配套的高磁异常区,是寻找火山岩型含锰磁铁矿的重要方向,可能伴生铜-多金属矿化。 相似文献
110.
西藏当雄地区拉屋矿床磁黄铁矿Re-Os同位素测年
和成矿物质来源示踪 总被引:1,自引:0,他引:1
拉屋矿床位于西藏自治区当雄县境内,大地构造位置处于冈底斯成矿区申扎-旁多铜、银、铅、锌、金成矿带,为大型矽卡岩型铜铅多金属矿床。在系统研究拉屋矿床地质地球化学特征的基础上,以矿石的磁黄铁矿为对象,测定Re-Os同位素年龄,获得等时线年龄数据为(309±31)Ma,187Os/188Os的初始值为0.51±0.12,γOs值为306.90~880.29,Re/Os为20.46~80.46。上述结果,结合矿区野外地质特征和稳定同位素特征,证明拉屋矿床主要形成于晚石炭世来故期,其成矿物质来源于地幔,并在喷流过程中与地壳海底卤水汇合,遭受了壳源物质的混染,形成喷流成因矽卡岩型矿床。 相似文献